Research Article  Open Access
Eman S. AlHwaitat, Sami H. Mahmood, Mahmoud Al–Hussein, Ibrahim Bsoul, "Structural and Magnetic Properties of Ba_{3}[Cu_{0.8−x}Zn_{x}Mn_{0.2}]_{2}Fe_{24}O_{41} ZType Hexaferrites", Advances in Materials Science and Engineering, vol. 2018, Article ID 6152020, 11 pages, 2018. https://doi.org/10.1155/2018/6152020
Structural and Magnetic Properties of Ba_{3}[Cu_{0.8−x}Zn_{x}Mn_{0.2}]_{2}Fe_{24}O_{41} ZType Hexaferrites
Abstract
We report on the synthesis and characterization of Ba_{3}[Cu_{0.8−x}Zn_{x}Mn_{0.2}]_{2}Fe_{24}O_{41} (x = 0.0, 0.2, 0.4, 0.6, and 0.8) barium hexaferrites. The samples were prepared by highenergy ballmilling technique and doublesintering approach. The effects of Zn substitution for Cu on the structural and magnetic properties of the prepared samples were investigated using Xray diffraction (XRD), scanning electron microscopy (SEM), and vibrating sample magnetometer (VSM). XRD patterns of the samples revealed the presence of a major Ztype hexaferrite phase, together with secondary Mtype and Ytype phases. The magnetic results indicated that the saturation magnetization increased slightly with increasing the Zn content, while the coercivity and magnetocrystalline anisotropy field exhibited a decreasing tendency with the increase of Zn content. The thermomagnetic curves revealed the complex magnetic structure of the prepared samples and confirmed that the Curie temperature of the magnetic phases decreased with increasing x as a result of the reduction of the strength of the superexchange interactions.
1. Introduction
The demands of rapidly developing modern technologies have driven and directed the efforts of a large sector of scientists and engineers toward the search for new materials with improved performance for miniaturized highfrequency devices [1]. Hexaferrites belonging to an important class of magnetic oxides have demonstrated potential for a plethora of permanent magnets as well as soft magnetic materials applications due to their favorable properties including chemical stability, low eddy current losses, and costeffectiveness [2–10]. Ztype hexaferrites had attracted a great attention due to their high permeability in frequency regions higher than 300 MHz, and cutoff frequency up to 2 GHz, rendering these materials promising for inductive core at microwave frequencies, and ultrahighfrequency communications devices [1, 11–13].
Synthesis of a pure phase of Ztype barium hexaferrite is a difficult process which involves a progressive transformation through intermediate ferrites before achieving the final complex crystalline structure [14–16]. This structure can be viewed as the sum of two simpler hexagonal ferrites, namely, Mtype (BaFe_{12}O_{19}) and Ytype (Ba_{2}Me_{2}Fe_{12}O_{22}), which crystallize prior to the formation of the Z phase through solidstate reaction [11]. Accordingly, realization of the Ztype ferrite may occur through topotactic reaction involving alternate stacking of platelets of simpler hexagonal ferrite phases [2, 17].
The magnetic and dielectric properties of hexaferrites can be tuned by controlled substitution scenarios for the divalent (Me^{2+}) or trivalent (Fe^{3+}) ions [12, 16]. It was reported that specific choices of divalent metal ions in Ztype hexaferrite may improve their properties [12, 18–23]. Specifically, the substitution of Co^{2+} by Cu^{2+}, Zn^{2+}, and Ni^{2+} ions was adopted for enhancing the electromagnetic properties of Co_{2}Z for miniaturized antenna applications [24], where the substitution of Zn^{2+} improves the saturation magnetization, while the substitution of Cu^{2+} lowers the sintering temperature. Also, Cu and Znsubstituted Co_{2}Z hexaferrite demonstrated improved properties for multilayer chip inductor applications [25, 26]. In addition, various scenarios of Cu and/or Mn substitutions were adopted in the synthesis of Mtype and Ytype hexaferrites (which are intermediate components of Ztype hexaferrites) and were reported to modify the magnetic properties of these hexaferrites for potential practical applications [27–37]. Also, the substitution of Co by Zn in Co_{2}Z hexaferrite demonstrated an increase in saturation magnetization, initial permeability, and resistivity, which makes Znsubstituted Co_{2}Z hexaferrites potentially important materials for highfrequency microchip inductor components [38, 39]. Further, the substitution of Mn for Fe in Co_{2}Z was reported to induce a shift of the relaxation peak in the dielectric behavior of Co_{2}Z hexaferrites toward higher frequencies [22].
Previous experimental results revealed that the optimal sintering temperature for the synthesis of Ztype hexaferrites using conventional solidstate method was in the range of 1200°C–1350°C [40]. Lower sintering temperatures of 1150°C–1200°C, however, were sufficient for the production of Ztype hexaferrites using wet chemical methods [13, 24, 40, 41]. The difficulty of obtaining a pure Ztype phase, and its tendency to coexist with other (M, Y, and Wtype) hexaferrites and spinel phases, has led to adopting different modified synthesis routes, where synthesis of pure Co_{2}Z hexaferrite was reported to be achieved at 1250°C sintering temperature [42, 43]. Also, it was reported that a Ztype phase can be obtained using twostep solidstate reaction where precursor materials are initially sintered at temperatures between 980 and 1180°C, then ground, and again sintered at about 1230–1300°C [23, 44].
In this study, divalent ion dopants Zn^{2+} and Mn^{2+} were incorporated into the structure of Cu_{2}Z hexaferrite to enhance the magnetic properties. The samples were prepared using twostep sintering solidstate reaction of raw materials. This method is suitable to produce highquality samples, since intermediate M and Y phases are formed at ∼ 1000°C, and topotactical reaction of these intermediate phases at higher sintering temperature is expected to lead to crystallization of the Ztype phase.
2. Experimental Techniques
Precursor powders of Ba_{3}[Cu_{0.8−x}Zn_{x}Mn_{0.2}]_{2}Fe_{24}O_{41} (x = 0, 0.2, 0.4, 0.6, and 0.8) were prepared by ballmilling stoichiometric ratios of the starting Fe_{2}O_{3}, CuO, ZnO, MnO, and BaCO_{3} powders. The starting powder mixtures were milled for 16 h at a rotational speed of 250 rpm in a planetary ballmill, using a powder to ball ratio of 1 : 12. The resulting powder was preheated to 1000°C, and then ground for 1 h and pressed into disks of ∼1 cm diameter and ∼2 mm thickness under a force of 50 kN. The disks were then sintered at 1200°C for 2 h in air using a heating rate of 10°C/min.
The structure of the samples was investigated by Xray diffraction (XRD), using a 7000 Xray diffractometer, with CuK_{α} radiation (λ = 0.154 nm). XRD patterns for the samples were recorded over the angular range 20° < 2θ < 70° with scanning step of 0.01° and scan speed 0.5 deg./min. A powder diffraction software package was used to identify the structural phases in the prepared samples. The morphology of the prepared samples was examined using scanning electron microscope (SEM), and the sample composition was examined by energydispersive Xray spectroscopy (EDX). The magnetic measurements were carried out at room temperature in an applied field up to 10 kOe using a vibrating sample magnetometer (VSM). The sample for VSM measurements was needleshaped to reduce sample shape anisotropy.
3. Results and Discussion
3.1. XRD Results
Figure 1 shows the diffraction patterns of Ba_{3}[Cu_{0.8−x}Zn_{x}Mn_{0.2}]_{2}Fe_{24}O_{41}. Rietveld analysis of the patterns using FullProf software indicated that the samples generally consisted of mixtures of the BaM hexaferrite phase, Ytype hexaferrite phase, and Ztype hexaferrite phase. The diffraction peaks corresponding to M and Ytype intermediate phases were relatively strong in the sample with x = 0, and their intensities seemed to be weakened by Zn substitution for Cu, especially at x = 0.2–0.6, indicating the production of Ztype hexaferrites with higher purity at these compositions. Although noticeable changes of the relative intensities of the diffraction peaks of Ztype hexaferrites were observed as a consequence of Zn and Mn substitution, the structure remained consistent with the standard pattern. These results indicated that while the highpurity Ztype phase was not successfully achieved in the twoend binary compounds [Cu_{0.8}Mn_{0.2}]_{2}Z and [Zn_{0.8}Mn_{0.2}]_{2}Z, the ternary [Cu,Zn,Mn]_{2}Z ferrites crystallized with high purity at sintering temperature of 1200°C, which is lower than the sintering temperature of 1250°C, 1300°C used for the production of the Ztype hexagonal phase by the solgel autocombustion method and ballmilling method, respectively [45]. The enhancement of the relative intensity of the (0018) reflection at 30.8° in comparison with the relative intensity of the corresponding reflection in the standard powder diffraction pattern is an indication that the possibility of crystallographic texture along the caxis in these samples cannot be excluded. This result is consistent with the results reported by others [1, 46].
The refined lattice parameters and cell volume of the Ztype hexaferrite phase in the samples, as well as the bulk density and Xray density, are listed in Table 1. The bulk densities of the samples were measured using Archimedes’ principle, while the Xray density of each sample was determined using the relation:where is the number of molecules per unit cell, is the molecular weight, is the cell volume, and is Avogadro’s number.

The lattice parameter a of the Ztype phase remains almost constant (5.88 ± 0.02 Å) with substitution, while c revealed a maximum value at x = 0.4. The cell volume (V) fluctuated (within ∼1.5%) with a tendency to increase with the increase of x. The increasing trend of cell parameters and cell volume can be associated with the substitution of Cu^{2+} by Zn^{2+} with larger ionic radius [47], whereas the unsystematic fluctuations of these parameters can be associated with uncontrolled lattice distortions in the respective samples [32].
The bulk density of sintered disk samples was found to be in the range of (4.91 ± 0.06) g/cm^{3} for all samples except that with x = 0.2, which demonstrated a relatively higher density of 5.22 g/cm^{3}. The Xray density remains almost constant in the range (5.37 ± 0.04) g/cm^{3} for the Z phase in all samples. These results indicated that our synthesis route yielded highly dense magnets (≥90% of theoretical density) for all compositions. The small decrease in Xray density for the sample with x = 0.4 can be attributed to the small increase in the cell volume. The Xray density of the Ztype phase in the samples is consistent with the reported value of 5.37 g/cm^{3} for Zn_{2}Z hexaferrite [48].
3.2. SEM and EDX Results
Typical SEM images were collected for each sample to investigate the particle shape and particle size distribution. Furthermore, EDX measurements at randomly selected spots of the samples were carried out to identify the particular hexaferrite phase to which the measured particle belongs. In some cases, the results of EDX measurements on different spots of the same sample were discussed for comparison, limiting our discussion to special cases for brevity purposes, and clarification of the main findings.
Figure 2(a) shows SEM image for the Ba_{3}[Cu_{0.8−x}Zn_{x}Mn_{0.2}]_{2}Fe_{24}O_{41} (x = 0) sample. The SEM image shows platelets with varying sizes in the range of 4 to 11 µm, including a large hexagonal platelet with sharp edges. Discontinuous grain growth (DGG) could be responsible for the occurrence of anomalously large hexagonal crystals in this sample [2]. Also, the SEM image shows small irregular particles which could be due to poor crystallization of starting components or as a result of the fractured surface of the sample.
(a)
(b)
To check the chemical composition of the particles, EDX spectra were collected at different spots of the sample. A typical spectrum collected from the encircled spot is shown in Figure 2(b), and the atomic ratios are presented in Table 2. The observed Ba : Fe atomic ratio of 1 : 8.04 is in excellent agreement with the stoichiometric ratio of 1 : 8.00 for Ba_{3}[Cu_{0.8}Mn_{0.2}]_{2}Fe_{24}O_{41} hexaferrite. Also, the observed Ba : Cu and Ba : Mn atomic ratios of 1 : 0.66 and 1 : 0.10 are close to the stoichiometric ratios of 1 : 0.53 and 1 : 0.13, respectively, for Ba_{3}[Cu_{0.8}Mn_{0.2}]_{2}Fe_{24}O_{41} hexaferrite.

For reproducibility purposes, EDX measurements were carried out at two different spots of the same sample. The measured Ba : Fe atomic ratios were 1 : 9.00 and 1 : 7.00, the Ba : Cu ratios were 1 : 0.64 and 1 : 0.80, and the Ba : Mn atomic ratios were 1 : 0.17 and 1 : 0.12. The average ratio of Ba : (Fe + Cu + Mn) in the two regions is 1 : 8.87, which agrees well with the theoretical value of 1 : 8.67 for Ba_{3}[Cu_{0.8}Mn_{0.2}]_{2}Fe_{24}O_{41}hexaferrite.
Figure 3 shows two SEM images (a, b) for Ba_{3}[Cu_{0.8−x}Zn_{x}Mn_{0.2}]_{2}Fe_{24}O_{41} (x = 0.2) sample. Sharpedged hexagonal platelets with inplane dimensions of several micrometers are observed in Figure 3(a), while much larger hexagonal platelets evolving through the DGG process are observed in Figure 3(b). The majority of the sample, however, is composed of large, nonparticulate masses, which may explain the appreciable increase in sample density. EDX spectra (not shown) were collected at different measuring spots to examine the chemical composition of the sample. The observed Ba : Fe atomic ratios at two different measuring spots were (1 : 7.00) and (1 : 8.00), while the atomic ratios of Ba : Zn were 1 : 0.22 and 1 : 0.14, the atomic ratios of Ba : Cu were 1 : 0.56 and 1 : 0.52, and the atomic ratios of Ba : Mn were 1 : 0.15 and 1 : 0.16. These atomic ratios are in agreement with the stoichiometric Ba : Fe ratio of 1 : 8.00, Ba : Zn ratio of 1 : 0.13, Ba : Cu ratio of 1 : 0.40, and Ba : Mn ratio of 1 : 0.13 for Ba_{3}[Cu_{0.6}Zn_{0.2}Mn_{0.2}]_{2}Fe_{24}O_{41} hexaferrite. Also, the average Ba: metal, Ba : (Fe + Zn + Cu + Mn) ratio was 1 : 8.4, which is close to the theoretical value of 1 : 8.7 for Ba_{3}[Cu_{0.6}Zn_{0.2}Mn_{0.2}]_{2}Fe_{24}O_{41} hexaferrite.
(a)
(b)
(c)
(d)
(e)
The SEM image for Ba_{3}[Cu_{0.8−x}Zn_{x}Mn_{0.2}]_{2}Fe_{24}O_{41} (x = 0.4) sample in Figure 3(c) shows that a large fraction of the sample consists of sharpedged hexagonal platelets with typical inplane size of few micrometers, in addition to some larger particles and nonparticulate masses which may have evolved through DGG process. EDX measurements on a selected spot of the sample revealed that the Ba:Fe atomic ratio is 1 : 5.20, the Ba : Zn atomic ratio is 1 : 0.38, the Ba : Mn atomic ratio is 1 : 0.10, and the Ba : Cu atomic ratio is 1 : 0.47. These ratios are lower than the stoichiometric metal ratios in the Ztype phase and are closer to the stoichiometric Ba:metal ratios of 1 : 6.0, 1 : 0.4, 1 : 0.2, and 1 : 0.4, respectively, in Ba_{2}Cu_{0.8}Zn_{0.8}Mn_{0.4}Fe_{12}O_{22} Ytype hexaferrite. This result confirmed the presence of Ytype hexaferrite crystallizing in the form of separate particles.
Figure 3(d) shows a typical SEM image for the samples with x = 0.6, which also revealed the presence of a large fraction of sharpedged hexagonal platelets with a typical inplane size in the range of 1.5 to 4 μm, in addition to large layered formations which may have evolved through the DGG process and topotactical reactions. EDX measurement on a selected spot of the sample revealed that the atomic ratio of Ba : Fe was 1 : 8.0, while the atomic ratios of (Ba : Cu, Zn, Mn) were 1 : 0.16, 1 : 0.28, and 1 : 0.07, respectively. These ratios are in agreement with the Ba : Fe, Cu, Zn, and Mn atomic ratios 0f 1 : 8.0, 1 : 0.13, 1 : 0.40, and 1 : 0.13 for Ba_{3}[Cu_{0.2}Zn_{0.6}Mn_{0.2}]_{2}Fe_{24}O_{41} hexaferrite. EDX measurement on a different spot of this sample, however, revealed that the Ba : Fe ratio was 1 : 6.59, which is close to the Ba:Fe ratio of 1 : 6.0 in Ytype hexaferrite. This could be an evidence of the presence of traces of the Ytype hexaferrite phase in the form of separate particles.
Figure 3(e) shows a typical SEM image for the sample with x = 0.8, which revealed crystallization of mainly hexagonal platelets with almost similar inplane particle sizes in the range from 1.67 to 2.3 μm. EDX measurements on a selected spot of the sample demonstrated that the atomic ratios of Ba : Fe, Zn, and Mn were 1 : 7.0, 1 : 1.0, and 1 : 0.10. The Ba : Zn ratio is consistent with Zn_{2}Y (Ba_{2}Zn_{2}Fe_{12}O_{22}) stoichiometry, while the observed Ba : Fe and Ba : Mn ratios are between their corresponding stoichiometric ratios in Zn_{2}Y and Ba_{3}Zn_{1.6}Mn_{0.4}Fe_{24}O_{41} Ztype hexaferrite, which may indicate that the measured region of the sample contained a mixture of Ytype and Ztype hexaferrite phases.
3.3. VSM Results
3.3.1. Isothermal Magnetization
The magnetic properties of Ba_{3}[Cu_{0.8−x}Zn_{x}Mn_{0.2}]_{2}Fe_{24}O_{41}, x = 0, 0.2, 0.4, 0.6, and 0.8 samples were studied by VSM at room temperature in an applied field up to 10 kOe. The hysteresis loops of all samples (Figure 4) were typical smooth Sshaped curves revealing characteristics of relatively soft magnetic materials. An expanded view of the loops is shown in Figure 5, from which the remnant magnetization and coercive field for each sample were obtained directly. The saturation magnetization, however, was determined by applying the law of approach to saturation in the highfield range. In this range, the magnetization of the sample is dominated by magnetization rotation processes of the magnetic domains, where the magnetization is given by [49–51]:where is the spontaneous saturation magnetization of the domains per unit volume, is a constant representing the contributions of inclusions and microstress, is a constant representing the contributions of magnetocrystalline anisotropy, and is the forced magnetization term. For hexagonal crystals, the constant is given by
A plot of M versus 1/H^{2} in the field region 8 kOe < H < 10 kOe for each sample gave a straight line, indicating that the magnetization in this field range is dominated by the magnetocrystalline term. According to Equation (2), the intercept of the straight line with the Maxis determines the saturation magnetization, while the slope determines the constant B, from which the anisotropy field (H_{a}) can be determined using Equation (3). The magnetic parameters derived from the hysteresis loops are presented in Table 3. The metallic ions (Fe^{3+}, Mn^{2+}, Cu^{2+}, and Zn^{2+}) in the Ztype hexaferrite phase occupy 10 nonequivalent crystallographic sites, listed in Table 4 together with the number of metal ions per formula unit and magnetic sublattice spin orientation. The partial substitution of Cu^{2+} ions in Cu_{2}Z by Zn^{2+} or Mn^{2+} ions may lead to complex magnetic structure determined by the cationic preferential site occupation. The preferred site for Cu^{2+} ion is the tetrahedral site, while that for the Mn^{2+} ion is the octahedral site [52]. The Zn^{2+} ion generally prefers to occupy 4f_{IV} tetrahedral site, with some tendency to enter the 4f_{VI} octahedral site due to the large ionic diameter (0.74 Å) [53].


Figure 6 shows the effect of zinc content on the saturation magnetization and the coercivity of Ba_{3}[Cu_{0.8−x}Zn_{x}Mn_{0.2}]_{2}Fe_{24}O_{41}. The saturation magnetization M_{s} for the sample with x = 0.0 was found to be 45 emu/g, which is close to the value of 46 emu/g reported for Cu_{2}Z hexaferrite [48]. As x increases, the saturation magnetization demonstrated increasing tendency, reaching the value of 53 emu/g for the sample with x = 0.8. While this value is in good agreement with recently reported values of 52.9 emu/g for Zn_{2}Y hexaferrite [45], it is lower than previously reported values of 5859 emu/g [38, 48, 54]. Considering that the Znrich samples consist of a mixture of stoichiometric ratios of Zn_{2}Z, Zn_{2}Y, and Mtype hexaferrites, with Zn_{2}Z = Zn_{2}Y + M, the saturation magnetization of the sample can be calculated from the following formula:where , , and are the molecular weights of BaM, Zn_{2}Y, and Zn_{2}Z hexaferrites, respectively, and and are the saturation magnetizations of BaM and Zn_{2}Y hexaferrites, respectively. Using typical values of the saturation magnetization of 72 emu/g for BaM [55] and 35.2 emu/g for Zn_{2}Y [56], the calculated value of the saturation magnetization of the sample is ∼51 emu/g. The fluctuations (of ∼5%) of the observed values of Znsubstituted samples about the calculated value can be attributed to the presence of Cu and Mn ions in the lattice.
Figure 6 also shows that the coercivity decreased sharply at all levels of Zn substitution for Cu. In light of the XRD results, the magnetically hard BaM hexaferrite was one of the observed structural components of the sample with x = 0, which could be responsible for the relatively high coercivity of the sample. The significant reduction of the coercivity of the Znsubstituted samples could therefore be associated with the transformation of the hard BaM magnetic phase to the soft Ztype phase, whereas the fluctuations of the coercivity of the Znsubstituted samples could be due to differences of the microstructure and particle size as demonstrated by SEM imaging.
Figure 7 shows the behavior of the anisotropy field (H_{a}) with increasing Zn concentration (x). The value of H_{a} demonstrated decreasing tendency with zinc substitution, recording values of 5.61 and 6.05 kOe at x = 0.4 and x = 0.6, respectively. These values are in good agreement with the reported value of 5.6 kOe for Zn_{2}Z hexaferrites [54]. Also, the values of 8.58 kOe and 7.92 kOe for the samples with x = 0.2 and 0.8 are in reasonable agreement with previously reported values of 6.66 and 7.0 kOe for Zn_{2}Z hexaferrites [45].
The initial susceptibility (χ_{i}) and magnetic permeability (μ_{i}) of each sample was determined from the initial magnetization curve (not shown for brevity). The obtained values of these magnetic parameters are also listed in Table 3 for all samples under investigation. The data indicated that the magnetic permeability improved by zinc substitution for Cu, and the improvement reached 55% at x = 0.8. This improvement could be potentially important for microwave applications of these materials.
3.3.2. Thermomagnetic Measurements
Figure 8 shows thermomagnetic curves for Ba_{3}[Cu_{0.8−x}Zn_{x}Mn_{0.2}]_{2}Fe_{24}O_{41} samples at constants applied field of 100 Oe. A homogeneous sample with sharp magnetic phasetransition at the Curie temperature (T_{c}) should give a sharp peak in the derivative of the thermomagnetic curve at that temperature. The thermomagnetic curve for the sample with x = 0.0 exhibited magnetic transition at 336°C, and a second magnetic transition at 440°C, preceded by a Hopkinson peak at T = 424°C, which is an indicator of the existence of some small particles with superparamagnetic behavior near the Curie temperature [57]. In light of the reported values for the Curie temperatures of various pure hexaferrite phases (Table 5), the phase transition at 440°C is associated with the ferromagnetictoparamagnetic transition of the Cu_{2}Z phase. On the contrary, the magnetic transition associated with the peak in the derivative curve at 336°C is close to the reported magnetic transition temperature of Mn_{2}Y, where the difference between our value and those reported for the Mn_{2}Y phase could be due to the insufficiency of Mn and Cu content to form pure Mn_{2}Y. In addition, since the substitution of Fe by Cu in BaM was found to result in a decrease of the Curie temperature [32], the peak structure around 440°C could also be associated with ferromagnetictoparamagnetic transition in Cupartially substituted BaM.

The derivative curve for the sample with x = 0.2 exhibited a relatively strong and sharp peak at 370°C, which is associated with the Curie temperature of the Zn_{2}Z phase. The observed higher transition temperature (compared to reported value of 360°C), and the occurrence of another small peak at 402°C, could be associated with sample inhomogeneity, where different phases of Cusubstituted Zn_{2}Z coexist with Curie temperatures between the characteristics of Zn_{2}Z and Cu_{2}Z. Furthermore, the small peak at 440°C could be associated with magnetic transitions of BaM and pure Cu_{2}Z phases, and the small peak at 294°C is in good agreement with the transition temperature of the Mn_{2}Y phase.
The derivative curve for the sample with x = 0.4 exhibited a strong peak at 356°C, which is associated with the transition temperature of the pure Zn_{2}Z phase. Also, the small peak at 396°C is associated with the transition temperature of the (Cu,Zn)_{2}Z (Znsubstituted Cu_{2}Z) phase. On the contrary, the transition temperature at 227°C lies between the transition temperatures of Zn_{2}Y (130°C) and Mn_{2}Y (290°C) and could therefore be associated with the (Mn,Zn)_{2}Y phase.
The magnetic transition at 338°C for the sample with x = 0.6 could be associated with the Zn_{2}Z phase, while the magnetic transition at 383°C is associated with the (Cu,Zn)_{2}Z phase. Also, the thermomagnetic curve exhibited a small peak at 183°C, which can be associated with the Curie temperature of the (Mn,Zn)_{2}Y phase. Finally, the thermomagnetic curve for the sample with x = 0.8 exhibited a strong peak at 146°C, which is associated with the transition temperature of the Zn_{2}Y phase. The phase transitions at 329°C and 383°C could be associated with Zn_{2}Z phases with slightly different chemical stoichiometry. The transition temperature of 431°C, however, could be associated with BaM with partial substitution for Fe. The observed Curie temperatures of the different magnetic phases in the samples are listed in Table 6.

The above results indicated that the Curie temperature of the magnetic phases generally decreased with the increase of Zn content as a consequence of the reduction of the superexchange interaction. The absence of Hopkinson peaks in the thermomagnetic curves of the Znsubstituted samples is indicative of the disappearance of superparamagnetic particles due to particle growth, in agreement with SEM imaging results.
4. Conclusion
The doublesintering process was successful in producing highdensity [Cu_{0.8−x}Zn_{x}Mn_{0.2}]_{2}Z hexaferrites at a relatively low temperature of 1200°C. Intermediate levels of Zn substitution for Cu (0.2 ≤ x ≤ 0.6) was found to be suitable for the production of a highly pure Ztype phase with increased saturation magnetization and reduced coercivity and magnetocrystalline anisotropy. All samples were highly dense, with a record density of 97% observed for the sample with x = 0.2. DGG, and topotactical reactions were responsible for growth of large particles and nonparticulate masses in the samples. The thermomagnetic curves demonstrated the complexity of the fabricated materials and indicated that the samples consisted of different magnetic phases with Curie temperatures generally decreasing with the increase of Zn concentration, which leads to the reduction of the superexchange interactions.
Data Availability
The data used to support the findings of this study are available from the corresponding author upon request.
Conflicts of Interest
The authors declare that they have no conflicts of interest.
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Copyright © 2018 Eman S. AlHwaitat et al. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.